REFERENCES

1. Venkateswarlu, S.; Vallem, S.; Umer, M.; et al. Recent progress on MOF/MXene nanoarchitectures: a new era in coordination chemistry for energy storage and conversion. J. Energy. Chem. 2023, 86, 409-36.

2. Cao, P.; Liu, Y.; Zhang, Q.; Guo, C.; Li, J.; Zeng, Q. MXene/MOF composites: synergistic platforms for advanced energy, catalysis, and environmental applications. Coord. Chem. Rev. 2025, 545, 217018.

3. Gaba, L.; Siwach, P.; Aggarwal, K.; et al. Hybridization of metal-organic frameworks and MXenes: expanding horizons in supercapacitor applications. Adv. Colloid. Interface. Sci. 2024, 332, 103268.

4. Chen, C.; Shen, L.; Wang, B.; et al. Environmental applications of metal-organic framework-based three-dimensional macrostructures: a review. Chem. Soc. Rev. 2025, 54, 2208-45.

5. Kumar, S.; Jain, S.; Nehra, M.; Dilbaghi, N.; Marrazza, G.; Kim, K. Green synthesis of metal-organic frameworks: a state-of-the-art review of potential environmental and medical applications. Coord. Chem. Rev. 2020, 420, 213407.

6. Shi, Y.; Yang, Y.; Ge, S.; et al. Progress in advanced MOF-derived materials for the removal of organic and inorganic pollutants. Coord. Chem. Rev. 2025, 530, 216474.

7. Momtaz, E.; Amoozadeh, M.; Zarepour, A.; Khosravi, A.; Zarrabi, A.; Iravani, S. MXenes and MOFs for electrochemical reduction of carbon dioxide (CO2). RSC. Sustain. 2026, 4, 1731-59.

8. Hanan, A.; Lakhan, M. N.; Bibi, F.; et al. MOFs coupled transition metals, graphene, and MXenes: emerging electrocatalysts for hydrogen evolution reaction. Chem. Eng. J. 2024, 482, 148776.

9. Ullah, S.; Qin, Z.; Tariq, M.; et al. MOF/MXene composite for electrocatalysis: fundamentals, structure-activity relationship and energy conversion applications. Coord. Chem. Rev. 2026, 563, 218037.

10. Tahir, B.; Alraeesi, A.; Tahir, M. Metal-organic framework (MOF) integrated Ti3C2 MXene composites for CO2 reduction and hydrogen production applications: a review on recent advances and future perspectives. Front. Chem. 2024, 12, 1448700.

11. Bagyalakshmi, S.; Balamurugan, K.; Mathankumar, M.; Sivakami, A.; Devi, N. Exploring metal organic frameworks/MXene based composite for an environmental applications-A critical review. J. Mol. Struct. 2025, 1334, 141838.

12. Gopalakrishnan, M.; Kao-Ian, W.; Aupama, V.; et al. Metal-organic framework/mxene heterostructure and its derivatives as electrode materials for rechargeable Zn-based batteries: design strategies and perspectives. Chem. Eng. J. 2024, 484, 149624.

13. Guo, H.; Zhang, J.; Xu, M.; et al. Zeolite-imidazole framework derived nickel-cobalt hydroxide on ultrathin MXene nanosheets for long life and high performance supercapacitance. J. Alloys. Compd. 2021, 888, 161250.

14. Xiao, T.; Jin, J.; Zhang, Y.; et al. Rational construction of 2D/2D Ti3C2Tx/NiCo MOF heterostructure for highly efficient Li+ storage. Electrochim. Acta. 2022, 427, 140851.

15. Zheng, S.; Zhou, H.; Xue, H.; Braunstein, P.; Pang, H. Pillared-layer Ni-MOF nanosheets anchored on Ti3C2 MXene for enhanced electrochemical energy storage. J. Colloid. Interface. Sci. 2022, 614, 130-7.

16. Li, Q.; Jiao, Q.; Yan, Y.; et al. Optimized Co-S bonds energy and confinement effect of hollow MXene@CoS2/NC for enhanced sodium storage kinetics and stability. Chem. Eng. J. 2022, 450, 137922.

17. Feng, L.; Chen, J.; Li, Y.; et al. MXene-reinforced Sb@C nanocomposites with synergizing spatial confinement architecture enabled ultra-stable and fast lithium ion storage. Chem. Eng. J. 2024, 489, 151396.

18. Zhu, R.; Gu, Y.; Liu, L.; Lu, J.; Pang, H. Integration of conductive MOF and MXene for high-performance supercapacitor. New. J. Chem. 2024, 48, 10593-8.

19. Wang, W.; Batool, N.; Zhang, T.; et al. When MOFs meet MXenes: superior ORR performance in both alkaline and acidic solutions. J. Mater. Chem. A. 2021, 9, 3952-60.

20. Huang, T.; Huang, X.; Hu, C.; et al. MOF-derived Ni nanoparticles dispersed on monolayer MXene as catalyst for improved hydrogen storage kinetics of MgH. Chem. Eng. J. 2021, 421, 127851.

21. Xu, B.; Wang, X.; Li, Z.; Zhao, F.; Sun, D. Recent progress in the in-situ growth of metal-organic frameworks on carbon-based supports. Sci. China. Chem. 2026, 69, 2735-52.

22. Xu, B.; Zhao, F.; Li, Z.; et al. Regulated Ni3(HHTP)2 conjugated MOF nanorod array on GO support for elevated glucose sensing. Chem. Eng. J. 2026, 530, 173743.

23. Zong, H.; Qi, R.; Yu, K.; Zhu, Z. Ultrathin Ti2NTx MXene-wrapped MOF-derived CoP frameworks towards hydrogen evolution and water oxidation. Electrochim. Acta. 2021, 393, 139068.

24. Murtaza, M.; Farooq, K.; Shah, W. A.; Ahmad, I.; Waseem, A. Layered MOF supported on 2D delaminated MXene (Mo2Ti2C3) nanosheets boosted water splitting. Nanoscale. Adv. 2024, 6, 6317-27.

25. Lamiel, C.; Hussain, I.; Warner, J. H.; Zhang, K. Beyond Ti-based MXenes: a review of emerging non-Ti based metal-MXene structure, properties, and applications. Mater. Today. 2023, 63, 313-38.

26. Jiang, Q.; Lei, Y.; Liang, H.; Xi, K.; Xia, C.; Alshareef, H. N. Review of MXene electrochemical microsupercapacitors. Energy. Storage. Mater. 2020, 27, 78-95.

27. Oh, T.; Lee, S.; Kim, H.; Ko, T. Y.; Kim, S. J.; Koo, C. M. Fast and high-yield anhydrous synthesis of Ti3C2Tx MXene with high electrical conductivity and exceptional mechanical strength. Small 2022, 18, 2203767.

28. Lipatov, A.; Goad, A.; Loes, M. J.; et al. High electrical conductivity and breakdown current density of individual monolayer Ti3C2T MXene flakes. Matter 2021, 4, 1413-27.

29. Lipatov, A.; Bagheri, S.; Sinitskii, A. Metallic conductivity of Ti3C2Tx MXene confirmed by temperature-dependent electrical measurements. ACS. Mater. Lett. 2023, 6, 298-307.

30. Loes, M. J.; Bagheri, S.; Sinitskii, A. Layer-dependent gas sensing mechanism of 2D titanium carbide (Ti3C2Tx) MXene. ACS. Nano. 2024, acsnano.4c08225.

31. Kenaz, R.; Ghosh, S.; Lounasvuori, M.; et al. Optical, structural, and charge transport properties of individual Ti3C2Tx MXene flakes via micro-ellipsometry and beyond. ACS. Nano. 2025, 19, 35414-24.

32. Yang, X.; Xu, C.; Li, S.; et al. Thermal treatment for promoting interfacial interaction in Co-BDC/Ti3C2T hybrid nanosheets for hybrid supercapacitors. J. Colloid. Interface. Sci. 2022, 617, 633-40.

33. Zhao, L.; Dong, B.; Li, S.; et al. Interdiffusion reaction-assisted hybridization of two-dimensional metal-organic frameworks and Ti3C2Tx nanosheets for electrocatalytic oxygen evolution. ACS. Nano. 2017, 11, 5800-7.

34. Yang, X.; Tian, Y.; Li, S.; et al. Heterogeneous Ni-MOF/V2CTx-MXene hierarchically-porous nanorods for robust and high energy density hybrid supercapacitors. J. Mater. Chem. A. 2022, 10, 12225-34.

35. Saini, H.; Srinivasan, N.; Šedajová, V.; et al. Emerging MXene@metal-organic framework hybrids: design strategies toward versatile applications. ACS. Nano. 2021, 15, 18742-76.

36. Prabhakar Vattikuti, S. V.; Shim, J.; Rosaiah, P.; Mauger, A.; Julien, C. M. Recent advances and strategies in MXene-based electrodes for supercapacitors: applications, challenges and future prospects. Nanomaterials 2023, 14, 62.

37. Chen, Y.; Shi, Y.; Song, G.; Yang, B.; Pang, H. Compositing MXene with organic coordination frameworks (MOFs, COFs, and HOFs) for enhanced electrochemical performance. Next. Mater. 2025, 6, 100323.

38. Singha, A.; Pandey, P.; Sahu, A.; Qureshi, M. Ultrathin dielectric triggered charge injection dynamics for high-performance metal organic framework/MXene supercapacitors. J. Phys. Chem. Lett. 2024, 15, 2123-32.

39. Wu, G.; Sun, S.; Zhu, X.; Ma, Z.; Zhang, Y.; Bao, N. Microfluidic fabrication of hierarchical-ordered ZIF-L(Zn)@ Ti3C2Tx Core-sheath fibers for high-performance asymmetric supercapacitors. Angew. Chem. Int. Ed. 2021, 61, e202115559.

40. Xu, D.; Zhang, Z.; Tao, K.; Han, L. A heterostructure of a 2D bimetallic metal-organic framework assembled on an MXene for high-performance supercapacitors. Dalton. Trans. 2023, 52, 2455-62.

41. Fang, T.; Ma, J.; Dai, Y.; et al. 2D sandwich-like Co-MOF/MXene composites as self-reconstructive oxygen evolution electrocatalysts. ACS. Appl. Nano. Mater. 2025, 8, 3519-26.

42. Watwiangkham, A.; Zijdemans, P. A.; Hadsadee, S.; et al. Rational design of MXene/MOF heterostructures to suppress hydrogen evolution and mitigate dendrite growth in aqueous Zn-ion batteries: insights from DFT and MD studies. ACS. Appl. Mater. Interfaces. 2025, 17, 69245-56.

43. Yang, Z.; Weng, C.; Gao, X.; et al. In situ construction of Sn-based metal-organic frameworks on MXene achieving fast electron transfer for rapid lithium storage. Chem. Eng. J. 2024, 486, 150299.

44. Zhang, P.; Chen, J.; Feng, L.; Jiang, M.; Xu, B. Dual confinement of Si nanoparticles in a MXene/ZIF-8-derived carbon framework for lithium-ion batteries. ACS. Appl. Nano. Mater. 2022, 5, 12720-8.

45. Hu, R.; Sha, D.; Cao, X.; et al. Anchoring metal-organic framework-derived ZnTe@C onto elastic Ti3C2Tx MXene with 0D/2D dual confinement for ultrastable potassium-ion storage. Adv. Energy. Mater. 2022, 12, 2203118.

46. Liu, Y.; Shi, Z.; Liang, T.; et al. The mechanism of room-temperature oxidation of aHF-etched Ti3C2Tx MXene determined via environmental transmission electron microscopy and molecular dynamics. InfoMat 2024, 6, e12536.

47. Soomro, R. A.; Zhang, P.; Fan, B.; Wei, Y.; Xu, B. Progression in the oxidation stability of MXenes. Nano-Micro. Lett. 2023, 15, 108.

48. Chen, Y.; Cheng, J.; Wang, A.; et al. The enhanced performance of Li-ion batteries based on Co-MOF/MXene composites. Inorg. Chem. Commun. 2024, 159, 111793.

49. Gao, X.; Zheng, Y.; Chang, J.; et al. Universal strategy for preparing highly stable PBA/Ti3C2Tx MXene toward lithium-ion batteries via chemical transformation. ACS. Appl. Mater. Interfaces. 2022, 14, 15298-306.

50. Sun, L.; Sun, J.; Zhai, S.; et al. Homologous MXene-derived electrodes for potassium-ion full batteries. Adv. Energy. Mater. 2022, 12, 2200113.

51. Chen, X.; Wang, K.; Xie, K.; Tao, H.; Wang, Y. MXene-coated nickel ion-exchanged ZIF skeleton-cavity layered double hydroxides for supercapacitors. Energy. Fuels. 2022, 37, 763-73.

52. Zhang, X.; Yang, S.; Lu, W.; et al. MXenes induced formation of Ni-MOF microbelts for high-performance supercapacitors. J. Colloid. Interface. Sci. 2021, 592, 95-102.

53. Tamtam, M. R.; Vangala, S. P. K.; Subrahmanyeswara Rao, N.; Choi, G. S.; Shim, J. MXene-coupled Mn-V binary MOF: a dual approach to stability enhancement and capacitance amplification. Ceram. Int. 2026, 52, 15876-88.

54. Zhao, W.; Peng, J.; Wang, W.; et al. Interlayer hydrogen-bonded metal porphyrin frameworks/MXene hybrid film with high capacitance for flexible all-solid-state supercapacitors. Small 2019, 15, 1901351.

55. Manikandan, M.; Seyadu Abuthahir, P.; Senthilkumar, P.; Manikandan, E. Synthesis of a MXene/metal-organic framework composite for efficient supercapacitor and electrocatalytic CO2 reduction. ACS. Appl. Mater. Interfaces. 2025, 17, 51996-2009.

56. Leng, X.; Vattikuti, S. P.; Zeng, J.; et al. Bimetallic Ni-Mo-MOFs as multifunctional electrodes for high-performance supercapacitors and oxygen evolution reaction. Int. J. Hydrogen. Energy. 2026, 218, 153954.

57. Nazari, M.; Morsali, A. Trimetallic-organic framework/MXene composite as an oxygen evolution reaction electrocatalyst with elevated intrinsic activity. J. Mater. Chem. A. 2024, 12, 4826-34.

58. Xie, Y.; Liu, G.; Rao, Z.; et al. In situ growth of CoFe bimetallic MOFs on S-Mxene/NF composite substrate as an efficient electrocatalyst for OER. Energy. Fuels. 2025, 39, 23304-13.

59. Wang, Y.; Ding, M.; Rong, W.; Kong, S.; Yao, J. In situ growth of Fe-doped zeolitic imidazolate framework on MXene for boosting photodriven CO2 cycloaddition. Sep. Purif. Technol. 2024, 345, 127399.

60. Cabrero-Antonino, M.; Uscategui-Linares, A.; Ramírez-Grau, R.; et al. 2D/2D MOF/MXene schottky junction: prolonged carrier lifetime and enhanced hydrogen evolution efficiency. Angew. Chem. Int. Ed. 2025, 64, e202503860.

61. Shi, L.; Wu, C.; Wang, Y.; et al. Rational design of coordination bond connected metal organic frameworks/MXene hybrids for efficient solar water splitting. Adv. Funct. Mater. 2022, 32, 2202571.

62. Cao, B.; Liu, H.; Zhang, X.; et al. MOF-derived ZnS nanodots/Ti3C2Tx MXene hybrids boosting superior lithium storage performance. Nano. Micro. Lett. 2021, 13, 202.

63. Chen, A.; Wang, J.; Chen, L.; et al. Hydroxylated MXene-assisted in situ synthesis of ultrafine CoHCC nanoparticles for high-performance potassium-ion battery anodes. Energy. . Environ. Mater. 2026, e70447.

64. Yu, K.; Zhang, J.; Hu, Y.; Wang, L.; Zhang, X.; Zhao, B. Ni doped Co-MOF-74 synergized with 2D Ti3C2Tx MXene as an efficient electrocatalyst for overall water-splitting. Catalysts 2024, 14, 184.

65. Liu, Y.; Pan, M.; Gong, M.; et al. Boosting redox kinetics in CoS/Ti3C2 heterostructure via interfacial charge redistribution for high-energy-density supercapacitors. Green. Energy. Environ. 2026, 11, 464-77.

66. Zhang, H.; Cao, W.; Wang, J.; et al. 2D conductive MOFs intercalated in MXene interlayer for fast and trace detection of triethylamine at room temperature. Adv. Sci. 2025, 12, 2500786.

67. Adil, M.; Olabi, A. G.; Abdelkareem, M. A.; et al. In-situ grown metal-organic framework derived CoS-MXene pseudocapacitive asymmetric supercapacitors. J. Energy. Storage. 2023, 60, 106537.

68. Jiang, G.; Zheng, N.; Chen, X.; et al. In-situ decoration of MOF-derived carbon on nitrogen-doped ultrathin MXene nanosheets to multifunctionalize separators for stable Li-S batteries. Chem. Eng. J. 2019, 373, 1309-18.

69. Yu, T.; Li, S.; Zhang, L.; et al. In situ growth of ZIF-67-derived nickel-cobalt-manganese hydroxides on 2D V2CTx MXene for dual-functional orientation as high-performance asymmetric supercapacitor and electrochemical hydroquinone sensor. J. Colloid. Interface. Sci. 2023, 629, 546-58.

70. Li, P.; Chong, X.; Guo, Y.; et al. Heterostructure-engineered conductive MOFs coupled with MoSe2@MXene framework for efficient and selective lithium extraction from salt lake brine via capacitive deionization. Adv. Sci. 2026, 13, e21830.

71. Ji, Y.; Li, W.; You, Y.; Xu, G. In situ synthesis of M (Fe, Cu, Co and Ni)-MOF@MXene composites for enhanced specific capacitance and cyclic stability in supercapacitor electrodes. Chem. Eng. J. 2024, 496, 154009.

72. Liu, J.; Xia, Q.; Wang, L.; Hu, Q.; Shinde, N. M.; Zhou, A. In situ growth of nanorod-shaped Ni,Co-MOF on Mo2CTx MXene surface to realize enhanced energy storage for supercapacitors. ACS. Appl. Mater. Interfaces. 2024, 16, 49380-91.

73. Wei, J.; Hu, F.; Pan, Y.; Lv, C.; Bian, L.; Ouyang, Q. Design strategy for metal-organic framework assembled on modifications of MXene layers for advanced supercapacitor electrodes. Chem. Eng. J. 2024, 481, 148793.

74. Yue, L.; Chen, L.; Wang, X.; et al. Ni/Co-MOF@aminated MXene hierarchical electrodes for high-stability supercapacitors. Chem. Eng. J. 2023, 451, 138687.

75. Stock, N.; Biswas, S. Synthesis of metal-organic frameworks (MOFs): routes to various MOF topologies, morphologies, and composites. Chem. Rev. 2011, 112, 933-69.

76. Meng, Y.; Yue, F.; Zhang, S.; et al. Zr-MOF/MXene composite for enhanced photothermal catalytic CO2 reduction in atmospheric and industrial flue gas streams. Carbon. Capture. Sci. Technol. 2024, 13, 100274.

77. Ren, Y.; Zhai, Q.; Wang, B.; et al. Synergistic adsorption-electrocatalysis of 2D/2D heterostructure toward high performance Li-S batteries. Chem. Eng. J. 2022, 439, 135535.

78. Huang, P.; Ying, H.; Zhang, S.; Zhang, Z.; Han, W. Multidimensional synergistic architecture of Ti3C2 MXene/CoS2@N-doped carbon for sodium-ion batteries with ultralong cycle lifespan. Chem. Eng. J. 2022, 429, 132396.

79. Wu, W.; Liu, T.; Diwu, J.; Li, C.; Zhu, J. Metal-organic framework-derived NiCo2S4@Co3S4 yolk-shell nanocages/ Ti3C2Tx MXene for high-performance asymmetric supercapacitors. J. Alloys. Compd. 2023, 954, 170213.

80. Tan, P.; Gao, R.; Zhang, Y.; et al. Electrostatically directed assembly of two-dimensional ultrathin Co2Ni-MOF/Ti3C2Tx nanosheets for electrocatalytic oxygen evolution. J. Colloid. Interface. Sci. 2023, 630, 363-71.

81. Qi, J. Q.; Huang, M. Y.; Ruan, C. Y.; et al. Construction of CoNi2S4 nanocubes interlinked by few-layer Ti3C2Tx MXene with high performance for asymmetric supercapacitors. Rare. Metals. 2022, 41, 4116-26.

82. Xie, W.; Wang, Y.; Zhou, J.; et al. MOF-derived CoFe2O4 nanorods anchored in MXene nanosheets for all pseudocapacitive flexible supercapacitors with superior energy storage. Appl. Surf. Sci. 2020, 534, 147584.

83. Guo, H.; Zhang, J.; Yang, F.; et al. Sandwich-like porous MXene/Ni3S4/CuS derived from MOFs as superior supercapacitor electrode. J. Alloys. Compd. 2022, 906, 163863.

84. Zhang, H.; Li, Z.; Hou, Z.; et al. Self-assembly of MOF on MXene nanosheets and in-situ conversion into superior nickel phosphates/MXene battery-type electrode. Chem. Eng. J. 2021, 425, 130602.

85. Zou, H.; He, B.; Kuang, P.; Yu, J.; Fan, K. Metal-organic framework-derived nickel-cobalt sulfide on ultrathin Mxene nanosheets for electrocatalytic oxygen evolution. ACS. Appl. Mater. Interfaces. 2018, 10, 22311-9.

86. Zong, H.; Hu, L.; Wang, Z.; Qi, R.; Yu, K.; Zhu, Z. Metal-organic frameworks-derived CoP anchored on MXene toward an efficient bifunctional electrode with enhanced lithium storage. Chem. Eng. J. 2021, 416, 129102.

87. Liu, X.; Liu, Z.; Yang, W.; et al. In situ fragmented and confined CoP nanocrystals into sandwich-structure MXene@CoP@NPC heterostructure for superior sodium-ion storage. Mater. Today. Chem. 2022, 26, 101002.

88. Liu, X.; Liu, F.; Zhao, X.; Fan, L. Constructing MOF-derived CoP-NC@MXene sandwich-like composite by in-situ intercalation for enhanced lithium and sodium storage. J. Materiomics. 2022, 8, 30-7.

89. Murtaza, M.; Farooq, K.; Shah, W. A.; Waseem, A. CoBDC MOF derived CoP/C couple with 2D Nb2CTx MXene as an efficient bifunctional catalyst for water splitting. Fuel 2025, 394, 135095.

90. Farooq, K.; Yang, Z.; Murtaza, M.; et al. MXene-enhanced metal-organic framework-derived CoP nanocomposites as highly efficient trifunctional electrocatalysts for OER, HER, and ORR. Adv. Energy. Sustain. Res. 2025, 6, 2400400.

91. Xiao, T.; Zhang, Y.; Xi, W.; et al. Rationally designing a Ti3C2Tx/CNTs-Co9S8 heterostructure as a sulfur host with multi-functionality for high-performance lithium-sulfur batteries. Nanoscale 2022, 14, 16139-47.

92. Ruan, C.; Zhu, D.; Qi, J.; et al. MXene-modulated CoNi2S4 dendrite as enhanced electrode for hybrid supercapacitors. Surf. Interfaces. 2021, 25, 101274.

93. Wen, Y.; Rufford, T. E.; Chen, X.; et al. Nitrogen-doped Ti3C2Tx MXene electrodes for high-performance supercapacitors. Nano. Energy. 2017, 38, 368-76.

94. Zhang, C.; Wang, L.; Lei, W.; et al. Achieving quick charge/discharge rate of 3.0 V s-1 by 2D titanium carbide (MXene) via N-doped carbon intercalation. Mater. Lett. 2019, 234, 21-5.

95. Jiang, J.; Xi, C.; Zhao, Y.; et al. MXene-based hierarchical electron coupling engineering of F-doped NiFe LDH/MOF-74 electrocatalysts for efficient overall water splitting. ACS. Catal. 2025, 15, 2561-75.

96. Niu, H.; Yan, Y.; Jiang, S.; et al. Interfaces decrease the alkaline hydrogen-evolution kinetics energy barrier on NiCoP/Ti3C2Tx MXene. ACS. Nano. 2022, 16, 11049-58.

97. Natu, V.; Benchakar, M.; Canaff, C.; Habrioux, A.; Célérier, S.; Barsoum, M. W. A critical analysis of the X-ray photoelectron spectra of Ti3C2Tz MXenes. Matter 2021, 4, 1224-51.

98. Wen, C.; Guo, D.; Zheng, X.; Li, H.; Sun, G. Hierarchical n MOF-867/MXene nanocomposite for chemical adsorption of polysulfides in lithium-sulfur batteries. ACS. Appl. Energy. Mater. 2021, 4, 8231-41.

99. Wang, Y.; Song, J.; Wong, W. Y. Constructing 2D sandwich-like MOF/MXene heterostructures for durable and fast aqueous zinc-ion batteries. Angew. Chem. Int. Ed. 2023, 62, e202218343.

100. Sun, K.; Shen, Y.; Min, J.; et al. MOF-derived Zn/Co co-doped MnO/C microspheres as cathode and Ti3C2@Zn as anode for aqueous zinc-ion full battery. Chem. Eng. J. 2023, 454, 140394.

101. Kao, Y.; Young, C. Trimetallic oxide catalysts from metal-organic frameworks on Ti3C2Tx MXene for enhanced water splitting. Int. J. Hydrogen. Energy. 2025, 100, 704-12.

102. Liang, X.; Ren, X.; Yang, Q.; et al. A two-dimensional MXene-supported metal-organic framework for highly selective ambient electrocatalytic nitrogen reduction. Nanoscale 2021, 13, 2843-8.

103. Liu, Z.; Lv, H.; Zhang, Y.; et al. Synergistic etching and hydrogen bonding-induced self-assembly of MXene/MOF hybrid aerogel for flexible room-temperature gas sensing. ACS. Sens. 2024, 9, 3641-51.

104. Chang, Y.; Chen, M.; Fu, Z.; et al. Building porphyrin-based MOFs on MXenes for ppb-level NO sensing. J. Mater. Chem. A. 2023, 11, 6966-77.

105. Liu, Y.; He, Y.; Vargun, E.; Plachy, T.; Saha, P.; Cheng, Q. 3D porous Ti3C2 MXene/NiCo-MOF composites for enhanced lithium storage. Nanomaterials 2020, 10, 695.

106. He, J.; Wei, Y.; Zhai, T.; Li, H. Antimony-based materials as promising anodes for rechargeable lithium-ion and sodium-ion batteries. Mater. Chem. Front. 2018, 2, 437-55.

107. Liang, S.; Cheng, Y. J.; Zhu, J.; Xia, Y.; Müller-Buschbaum, P. A chronicle review of nonsilicon (Sn, Sb, Ge)-based lithium/sodium-ion battery alloying anodes. Small. Methods. 2020, 4, 2000218.

108. Sun, L.; Wang, H.; Zhai, S.; et al. Dual-conductive metal-organic framework@MXene heterogeneity stabilizes lithium-ion storage. J. Energy. Chem. 2023, 76, 368-76.

109. Hwang, J.; Myung, S.; Sun, Y. Sodium-ion batteries: present and future. Chem. Soc. Rev. 2017, 46, 3529-614.

110. Xu, E.; Li, P.; Quan, J.; et al. Dimensional gradient structure of CoSe2@CNTs-MXene anode assisted by ether for high-capacity, stable sodium storage. Nano. Micro. Lett. 2021, 13, 40.

111. Wang, T.; Zeng, J.; Gu, X.; et al. In-situ growth of nitrogen-doped carbon nanotubes on MXene nanosheets for efficient sodium/potassium-ion storage. Front. Mater. 2023, 10, 1214543.

112. Shi, X.; Liang, W.; Liu, G.; et al. Electrode materials for Li/Na storage from mechanochemically synthesised MOFs/MXene composites: a solvent-free approach. Chem. Eng. J. 2023, 462, 142271.

113. Li, Y.; Wu, F.; Li, Y.; et al. Ether-based electrolytes for sodium ion batteries. Chem. Soc. Rev. 2022, 51, 4484-536.

114. Mane, R. S.; Mane, S.; Somkuwar, V.; Thombre, N. V.; Patwardhan, A. V.; Jha, N. A novel hierarchically hybrid structure of MXene and bi-ligand ZIF-67 based trifunctional electrocatalyst for zinc-air battery and water splitting. Battery. Energy. 2023, 2, 20230019.

115. Lu, H.; Hu, J.; Zhang, K.; et al. Microfluidic-assisted 3D printing zinc powder anode with 2D conductive MOF/MXene heterostructures for high-stable zinc-organic battery. Adv. Mater. 2023, 36, 2309753.

116. Ahmed, A. A.; Mirghni, A. A.; Hardianto, Y. P.; et al. Engineering a hierarchically porous manganese-based ternary composite for high-performance aqueous zinc-ion batteries. J. Inorg. Organomet. Polym. Mater. 2026, 4344.

117. Hosaka, T.; Kubota, K.; Hameed, A. S.; Komaba, S. Research development on K-ion batteries. Chem. Rev. 2020, 120, 6358-466.

118. Pathak, I.; Acharya, D.; Chhetri, K.; et al. Ti3C2Tx MXene integrated hollow carbon nanofibers with polypyrrole layers for MOF-derived freestanding electrodes of flexible asymmetric supercapacitors. Chem. Eng. J. 2023, 469, 143388.

119. Adil, M.; Olabi, A. G.; Abdelkareem, M. A.; et al. In-situ grown bimetallic FeCu MOF-MXene composite for solid-state asymmetric supercapacitors. J. Energy. Storage. 2023, 68, 107817.

120. Liu, C.; Bai, Y.; Li, W.; Yang, F.; Zhang, G.; Pang, H. In situ growth of three-dimensional MXene/metal-organic framework composites for high-performance supercapacitors. Angew. Chem. Int. Ed. 2022, 61, e202116282.

121. Dai, Y.; Sun, C.; Gul, H.; et al. Three-dimensional honeycomb composites consist of metal carbides and layered double hydroxides for high-performance supercapacitor electrode materials. J. Power. Sources. 2024, 602, 234306.

122. Shivade, D. S.; Kurade, A. N.; Bhosale, R. K.; et al. Folic acid-assisted in situ solvothermal synthesis of Ni-MOF/MXene composite for high-performance supercapacitors. J. Energy. Storage. 2024, 100, 113754.

123. Adil, M.; Olabi, A. G.; Abdelkareem, M. A.; Alawadhi, H.; Shinde, P. A.; Rodriguez, C. Engineering MXene-Fe MOF interfaces through in-situ growth for high-performance hybrid supercapacitors. J. Power. Sources. 2026, 666, 239129.

124. Han, Y.; Liu, Z.; Wang, C.; Guo, L.; Wang, Y. Construction of rod-like cobalt-pyridinedicarboxylic acid/MXene nanosheets composites for hydrogen evolution reaction and supercapacitor. J. Colloid. Interface. Sci. 2024, 661, 139-49.

125. Wang, J.; Gong, J.; Zhang, H.; Lv, L.; Liu, Y.; Dai, Y. Construction of hexagonal nickel-cobalt oxide nanosheets on metal-organic frameworks based on MXene interlayer ion effect for hybrid supercapacitors. J. Alloys. Compd. 2021, 870, 159466.

126. Du, Z.; Liu, W.; Liu, J.; et al. A thermally chargeable supercapacitor based on the g-C3N4-doped PAMPS/PAA hydrogel solid electrolyte and 2D MOF@Ti3C2Tx MXene heterostructure composite electrode. Adv. Mater. Inter. 2023, 10, 2300266.

127. Li, S.; Wang, Y.; Li, Y.; Xu, J.; Li, T.; Zhang, T. In situ growth of Ni-MOF nanorods array on Ti3C2Tx nanosheets for supercapacitive electrodes. Nanomaterials 2023, 13, 610.

128. Zhang, Y.; Zhu, X.; Sun, S.; Guo, Q.; Xu, M.; Wu, G. Ordered interface engineering enabled high-performance Ti3C2Tx MXene fiber-based supercapacitors. Energy. Fuels. 2022, 36, 7898-907.

129. Shingte, S.; Chavan, V.; Dhavale, R.; et al. Optimizing supercapacitive performance of MXene through MOF-derived nickel ferrite nanoparticle integration. J. Energy. Storage. 2024, 92, 112169.

130. Maity, S.; Bera, S.; Kapuria, A.; Debnath, A.; Das, S.; Saha, S. K. MXene derived metal organic framework@PANI heterostructure as a hybrid supercapacitor. Mater. Today. Chem. 2025, 45, 102690.

131. Tamtam, M. R.; Karri, R. R.; Choi, G. S.; Shim, J. MXene-integrated Mn Co bimetallic MOF hybrids for enhanced solid-state supercapacitor performance. J. Energy. Storage. 2026, 154, 120355.

132. Movafagh, R.; Ghamari, F.; Shi, H.; Arjomandi, J. Template-assisted construction of NiCo-MOF/MXene nanocomposite based on poly p-nitroaniline as efficient electrode material for symmetric and asymmetric hybrid supercapacitors. J. Energy. Storage. 2026, 141, 119321.

133. Gogotsi, Y.; Simon, P. True Performance Metrics in Electrochemical Energy Storage. Science 2011, 334, 917-8.

134. Roger, I.; Shipman, M. A.; Symes, M. D. Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting. Nat. Rev. Chem. 2017, 1, 0003.

135. Gu, W.; Wu, M.; Xu, J.; Zhao, T. MXene boosted metal-organic framework-derived Fe-N-C as an efficient electrocatalyst for oxygen reduction reactions. Int. J. Hydrogen. Energy. 2022, 47, 17224-32.

136. Zhang, J.; Zhang, W.; Zhang, J.; et al. MOF-derived bimetallic NiMo-based sulfide electrocatalysts for efficient hydrogen evolution reaction in alkaline media. J. Alloys. Compd. 2023, 935, 167974.

137. Pashajavid, S.; Mohammadi, T.; Hanifi, S.; Asghari, E.; Delibaş, N.; Niaei, A. Boosted oxygen evolution with engineering of mixed ligand Co metal-organic framework integrated on titanium carbide MXene support. Diamond. Relat. Mater. 2026, 166, 113762.

138. Farooq, K.; Murtaza, M.; Yang, Z.; Waseem, A.; Zhu, Y.; Xia, Y. MXene boosted MOF-derived cobalt sulfide/carbon nanocomposites as efficient bifunctional electrocatalysts for OER and HER. Nanoscale. Adv. 2024, 6, 3169-80.

139. Wen, Y.; Wei, Z.; Ma, C.; Xing, X.; Li, Z.; Luo, D. MXene boosted CoNi-ZIF-67 as highly efficient electrocatalysts for oxygen evolution. Nanomaterials 2019, 9, 775.

140. Tiwari, A. P.; Chandra, P.; Rahman, M. S.; Mirica, K. A.; Scheideler, W. J. Optimizing active sitesvia chemical bonding of 2D metal-organic frameworks and MXenes for efficient hydrogen evolution reaction activity. Nanoscale 2025, 17, 11028-36.

141. Mirghni, A. A.; Hardianto, Y. P.; Ferdous, A. R.; Shah, S. S.; Hossain, M. D.; Aziz, M. A. Scalable electrodeposition of NiMoP for alkaline hydrogen production: from catalyst design to full-cell performance. Electrochim. Acta. 2026, 572, 149291.

142. Li, S.; Chai, H.; Zhang, L.; Xu, Y.; Jiao, Y.; Chen, J. Constructing oxygen vacancy-rich MXene @Ce-MOF composites for enhanced energy storage and conversion. J. Colloid. Interface. Sci. 2023, 642, 235-45.

143. Felgenhauer, M.; Hamacher, T. State-of-the-art of commercial electrolyzers and on-site hydrogen generation for logistic vehicles in South Carolina. Int. J. Hydrogen. Energy. 2015, 40, 2084-90.

144. Buttler, A.; Spliethoff, H. Current status of water electrolysis for energy storage, grid balancing and sector coupling via power-to-gas and power-to-liquids: a review. Renew. Sustain. Energy. Rev. 2018, 82, 2440-54.

145. He, L.; Liu, J.; Hu, B.; et al. Cobalt oxide doped with titanium dioxide and embedded with carbon nanotubes and graphene-like nanosheets for efficient trifunctional electrocatalyst of hydrogen evolution, oxygen reduction, and oxygen evolution reaction. J. Power. Sources. 2019, 414, 333-44.

146. Huang, H.; Qin, J.; Liu, C.; et al. Constructing Zn-based MOF-MXene nanoarchitectures to stabilize ultrafine Pt nanocrystals with enhanced methanol oxidation performance. Carbon 2024, 226, 119171.

147. Voiry, D.; Chhowalla, M.; Gogotsi, Y.; et al. Best practices for reporting electrocatalytic performance of nanomaterials. ACS. Nano. 2018, 12, 9635-8.

148. Paul, J.; Kim, J. Reticular synthesis of a conductive composite derived from metal-organic framework and Mxene for the electrochemical detection of dopamine. Appl. Surf. Sci. 2023, 613, 156103.

149. Rodrigues, P.; Bangali, H.; Saleh, E. A. M.; et al. Metal-organic framework/MXene nanohybrid composites as an emerging electrochemical sensing platform for food safety and biomedical monitoring: from synthesis to application. Electrochim. Acta. 2024, 494, 144424.

150. Ramachandran, R.; Zhao, C.; Rajkumar, M.; et al. Porous nickel oxide microsphere and Ti3C2Tx hybrid derived from metal-organic framework for battery-type supercapacitor electrode and non-enzymatic H2O2 sensor. Electrochim. Acta. 2019, 322, 134771.

151. Peng, H.; Yang, J.; Lin, C.; Qi, L.; Li, L.; Shi, K. Gas-sensitive performance of metal-organic framework-derived CuO NPs/Ti3C2Tx MXene heterostructures for efficient NO2 detection at room temperature. J. Alloys. Compd. 2024, 980, 173657.

152. Ranjith, K. S.; Sonwal, S.; Mohammadi, A.; et al. Imparting hydrophobicity to a MOF on layered MXene for the selective, rapid, and ppb level humidity-independent detection of NH3 at room temperature. J. Mater. Chem. A. 2024, 12, 26132-46.

153. Wu, H. X.; Li, Y.; Chen, L. L.; et al. MXene-boosted nickel-based metal-organic framework composite with enhanced conductivity and catalytic activity for highly sensitive glucose detection. Rare. Metals. 2026, 45, e70442.

154. Boruah, P. K.; Sharma, N.; Das, M. R.; Ohtani, R.; Le Ouay, B.; Ohba, M. Metal-organic framework/Nb4C3Tx MXene composites for ultrasensitive detection of dopamine. Chem. Commun. 2024, 60, 7307-10.

155. Shen, B.; Hong, B.; Guo, X.; et al. Facile fabrication of sensing electrode based on CoFe-MOFs/MXene for ultrasensitive detection of picomolar chloramphenicol. Talanta 2025, 286, 127552.

156. Elancheziyan, M.; Manoj, D.; Bhuvanendran, N.; Harathi, J.; Lee, S. Y.; Won, K. CoFeMn-layered double hydroxide-decorated MXene for high-performance electrochemical sensing of ciprofloxacin in food and water samples. Microchim. Acta. 2026, 193, 255.

157. Kaur, G.; Sharma, S.; Bhardwaj, N.; Nayak, M. K.; Deep, A. Highly sensitive and selective electrochemical detection of Aflatoxin B1 in water and Pistachio samples with MOF/MXene composite based sensor. Food. Control. 2024, 165, 110694.

158. Xiao, P.; Zhu, G.; Shang, X.; et al. An Fe-MOF/MXene-based ultra-sensitive electrochemical sensor for arsenic(III) measurement. J. Electroanal. Chem. 2022, 916, 116382.

159. Cheng, D.; Li, P.; Zhu, X.; Liu, M.; Zhang, Y.; Liu, Y. Enzyme-free electrochemical detection of hydrogen peroxide based on thethree-dimensional flower-like Cu-based metal organic frameworks and MXene Nanosheets. Chin. J. Chem. 2021, 39, 2181-7.

160. Su, X.; You, Q.; Wang, P.; et al. MXene quantum dot functionalized bimetallic MOFs as a label-free aptasensor for highly sensitive detection of exosomes. J. Mater. Chem. C. 2024, 12, 8561-8.

161. Richard, B.; Niyas, K.; Ankitha, M.; Rasheed, P. A. Biological metal-organic framework-embedded MXene nanocomposite as a wearable transducer patch for real-time monitoring of the sleep hormone. ACS. Appl. Nano. Mater. 2024, 7, 9585-97.

162. Lv, L.; Kang, X.; Hua, L.; et al. Sandwich-type electrochemical immunosensor based on MXene/CNTs substrate and MOFs (MIL-101) probe for leather artifact identification. Microchem. J. 2025, 213, 113810.

163. Xie, Z.; Gao, Z.; Yu, T.; Du, J.; Qiu, J. Multifunctional MXene/MOF-derived foam for adaptive radar-infrared stealth and structural sensing. Adv. Funct. Mater. 2025, 36, e30008.

164. Xu, W.; Lu, Y.; Zhang, Z.; et al. MOF/MXene nanocomposite to improve thermal sensitivity and bending resistance of flexible temperature sensor for body temperature and respiration rate monitoring. IEEE. Sensors. J. 2024, 24, 9437-48.

165. Wang, D.; Zhang, D.; Yang, Y.; Mi, Q.; Zhang, J.; Yu, L. Multifunctional latex/polytetrafluoroethylene-based triboelectric nanogenerator for self-powered organ-like MXene/metal-organic framework-derived CuO nanohybrid ammonia sensor. ACS. Nano. 2021, 15, 2911-9.

166. Li, Y.; Liu, Y.; Wang, Z.; et al. In-situ growth of Ti3C2@MIL-NH2 composite for highly enhanced photocatalytic H2 evolution. Chem. Eng. J. 2021, 411, 128446.

167. Tian, P.; He, X.; Zhao, L.; et al. Enhanced charge transfer for efficient photocatalytic H2 evolution over UiO-66-NH2 with annealed Ti3C2Tx MXenes. Int. J. Hydrogen. Energy. 2019, 44, 788-800.

168. Wang, Q.; Domen, K. Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies. Chem. Rev. 2019, 120, 919-85.

169. Li, Z.; Fang, S.; Sun, H.; Chung, R. J.; Fang, X.; He, J. H. Solar hydrogen. Adv. Energy. Mater. 2023, 13, 2203019.

170. Chen, W.; Han, B.; Xie, Y.; Liang, S.; Deng, H.; Lin, Z. Ultrathin Co-Co LDHs nanosheets assembled vertically on MXene: 3D nanoarrays for boosted visible-light-driven CO2 reduction. Chem. Eng. J. 2020, 391, 123519.

171. Qin, J.; Liu, B.; Lam, K.; Song, S.; Li, X.; Hu, X. 0D/2D MXene quantum Dot/Ni-MOF ultrathin nanosheets for enhanced N2 photoreduction. ACS. Sustain. Chem. Eng. 2020, 8, 17791-9.

172. Yu, K.; Tang, L.; Cao, X.; et al. Semiconducting metal-organic frameworks decorated with spatially separated dual cocatalysts for efficient uranium(VI) photoreduction. Adv. Funct. Mater. 2022, 32, 2200315.

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